气候变化领域集成服务门户(CCPortal): Solvent system for effective near-term production of hydroxymethylfurfural (HMF) with potential for long-term process improvement

CCPortal

DOI	10.1039/c9ee00447e
	Solvent system for effective near-term production of hydroxymethylfurfural (HMF) with potential for long-term process improvement
	Motagamwala A.H.; Huang K.; Maravelias C.T.; Dumesic J.A.
发表日期	2019
ISSN	17545692
起始页码	2212
结束页码	2222
卷号	12 期号:7
英文摘要	Production of renewable chemicals to mitigate the deleterious effects of greenhouse gas emissions requires technologies that are cost-competitive with the fossil-fuel industry, require low capital investment, and produce high-value products. We report production of 5-hydroxymethylfurfural (HMF), a valuable platform molecule from biomass-derived carbohydrates at high yields (>90%) and with excellent carbon balance (>95%) using an inexpensive solvent system composed of acetone and water. We demonstrate that HMF, a thermally unstable molecule, can be separated from this low boiling solvent system with high recovery (96%) and purity (∼99%). We show that fructose is selectively dehydrated in this solvent system from a mixture of glucose and fructose, a property that can be leveraged to integrate the proposed process with current processes for the production of high fructose corn syrup. Techno-economic analysis indicates that utilizing fructose as feedstock leads to low investment (16 MM$) and produces HMF at a minimum selling price (MSP) of $1710 per ton. The MSP can be further reduced to $1460 per ton by changing the feedstock to glucose. © The Royal Society of Chemistry 2019.
英文关键词	Acetone; Economic analysis; Feedstocks; Fossil fuels; Fructose; Gas emissions; Glucose; Greenhouse gases; Investments; Molecules; 5 hydroxymethyl furfurals; Capital investment; Deleterious effects; High-fructose corn syrups; Hydroxymethylfurfural; Platform molecules; Renewable chemicals; Techno-Economic analysis; Solvents; chemical compound; fossil fuel; glucose; greenhouse gas; solvent; Zea mays
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189872
作者单位	Department of Chemical and Biological Engineering, University of Wisconsin-Madison, Madison, WI 53706, United States; DOE Great Lakes Bioenergy Research Center, University of Wisconsin-Madison, 1552 University Ave, Madison, WI 53726, United States
推荐引用方式 GB/T 7714	Motagamwala A.H.,Huang K.,Maravelias C.T.,et al. Solvent system for effective near-term production of hydroxymethylfurfural (HMF) with potential for long-term process improvement[J],2019,12(7).
APA	Motagamwala A.H.,Huang K.,Maravelias C.T.,&Dumesic J.A..(2019).Solvent system for effective near-term production of hydroxymethylfurfural (HMF) with potential for long-term process improvement.Energy & Environmental Science,12(7).
MLA	Motagamwala A.H.,et al."Solvent system for effective near-term production of hydroxymethylfurfural (HMF) with potential for long-term process improvement".Energy & Environmental Science 12.7(2019).