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DOI	10.1039/c9ee02311a
	Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries
	Li X.; Liang J.; Luo J.; Norouzi Banis M.; Wang C.; Li W.; Deng S.; Yu C.; Zhao F.; Hu Y.; Sham T.-K.; Zhang L.; Zhao S.; Lu S.; Huang H.; Li R.; Adair K.R.; Sun X.
发表日期	2019
ISSN	17545692
起始页码	2665
结束页码	2671
卷号	12 期号:9
英文摘要	Most inorganic solid-state electrolytes (SSEs) suffer from incompatibility with oxide cathode materials and instability in ambient air, presenting major barriers for their application in high performance all-solid-state batteries (ASSLBs). Herein, we report a rationally designed halide-based Li3InCl6 SSE with a high ionic conductivity of 1.49 × 10-3 S cm-1 (25 °C). The Li3InCl6 SSE is stable towards oxide cathode materials (e.g., LiCoO2) without any interfacial treatment. By applying the Li3InCl6 SSEs, significantly enhanced electrochemical performances are achieved in terms of capacity and durability. Experimental investigations reveal that the Li3InCl6 can avoid side reactions between the SSEs and the oxide cathode materials and thus effectively improve the Li+ migration across the interface. Moreover, Li3InCl6 is highly stable in ambient air and possesses good ionic conductivity retention after a reheating process, further making it an attractive electrolyte for next-generation ASSLBs. © 2019 The Royal Society of Chemistry.
英文关键词	Cathodes; Chlorine compounds; Cobalt compounds; Indium compounds; Ionic conductivity; Lithium compounds; Solid state devices; Solid-State Batteries; All-solid state batteries; Electrochemical performance; Experimental investigations; Highly stables; Inorganic solids; Interfacial treatments; Reheating process; Side reactions; Solid electrolytes; chemical reaction; electrochemical method; electrode; electrolyte; experimental study; fuel cell; ionic composition; performance assessment; solid
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189826
作者单位	Department of Mechanical and Materials Engineering, University of Western Ontario, 1151 Richmond St, London, ON N6A 3K7, Canada; Canadian Light Source, 44 Innovation Boulevard, Saskatoon, SK S7N 2V3, Canada; Department of Chemistry, University of Western Ontario, 1151 Richmond St, London, ON N6A 3K7, Canada; China Automotive Battery Research Institute Co. Ltd, North Sanhuan Middle Road, Beijing, 100088, China; Glabat Solid-State Battery Inc., 700 Collip Circle, London, ON N6G 4X8, Canada
推荐引用方式 GB/T 7714	Li X.,Liang J.,Luo J.,et al. Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries[J],2019,12(9).
APA	Li X..,Liang J..,Luo J..,Norouzi Banis M..,Wang C..,...&Sun X..(2019).Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries.Energy & Environmental Science,12(9).
MLA	Li X.,et al."Air-stable Li3InCl6 electrolyte with high voltage compatibility for all-solid-state batteries".Energy & Environmental Science 12.9(2019).