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DOI	10.1039/c9ee00315k
	Recent advances in confining metal-based nanoparticles into carbon nanotubes for electrochemical energy conversion and storage devices
	Tabassum H.; Mahmood A.; Zhu B.; Liang Z.; Zhong R.; Guo S.; Zou R.
发表日期	2019
ISSN	17545692
起始页码	2924
结束页码	2956
卷号	12 期号:10
英文摘要	Nano-confinement of metal-based nanostructures in one-dimensional carbon nanotubes (M@CNTs) is an interesting and effective way to achieve new functional materials with unique physical and chemical properties for various energy applications with enhanced performance. In this unique structure, the inner cavity of CNTs can act as a nanoreactor with a diameter of a few nanometers and length in microns. The nano-confinement of metals into CNTs not only improves the local environment of CNTs but also prevents metal leaching and aggregation. This critical review summarizes recent advances in developing advanced nano-confinement methods for different functional nanoparticles, such as metals, metal oxides, metal sulfides, metal phosphides, metal carbides, etc. Particular attention is paid to their catalytic activities and stabilities, strategies for the enhancement of storage capacities of Zn-air batteries, Li-O2 batteries and lithium ion batteries. The demonstrated examples provide an understanding of M@CNTs for use as electrocatalysts and electrodes for batteries. Finally, challenges and future prospects of M@CNTs are highlighted for electrochemical energy conversion and storage devices. © 2019 The Royal Society of Chemistry.
英文关键词	Carbides; Carbon nanotubes; Catalyst activity; Electrocatalysts; Energy conversion; Functional materials; Lithium compounds; Lithium-air batteries; Lithium-ion batteries; Metals; Phosphorus compounds; Storage (materials); Sulfur compounds; Virtual storage; Zinc air batteries; Zinc compounds; Electrochemical energy conversions; Energy applications; Functional nanoparticles; Future prospects; Local environments; Metal phosphides; Physical and chemical properties; Storage capacity; Metal nanoparticles; carbon nanotube; catalysis; catalyst; electrochemical method; electrode; energy storage; equipment; leaching; metal; nanoparticle; performance assessment
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189798
作者单位	Beijing Key Lab of Theory and Technology for Advanced Battery Materials, Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, 100871, China; Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, 102249, China
推荐引用方式 GB/T 7714	Tabassum H.,Mahmood A.,Zhu B.,et al. Recent advances in confining metal-based nanoparticles into carbon nanotubes for electrochemical energy conversion and storage devices[J],2019,12(10).
APA	Tabassum H..,Mahmood A..,Zhu B..,Liang Z..,Zhong R..,...&Zou R..(2019).Recent advances in confining metal-based nanoparticles into carbon nanotubes for electrochemical energy conversion and storage devices.Energy & Environmental Science,12(10).
MLA	Tabassum H.,et al."Recent advances in confining metal-based nanoparticles into carbon nanotubes for electrochemical energy conversion and storage devices".Energy & Environmental Science 12.10(2019).