气候变化领域集成服务门户(CCPortal): Quantitative isotope measurements in heterogeneous photocatalysis and electrocatalysis

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DOI	10.1039/d0ee01790f
	Quantitative isotope measurements in heterogeneous photocatalysis and electrocatalysis
	Lin Y.; Deng C.; Wu L.; Zhang Y.; Chen C.; Ma W.; Zhao J.
发表日期	2020
ISSN	17545692
起始页码	2602
结束页码	2617
卷号	13 期号:9
英文摘要	Heterogeneous photocatalysis and electrocatalysis have attracted tremendous interest in energy chemistry including CO2 reduction, N2 fixation, water oxidation, oxygen reduction, organic transformations, etc. The molecular-level understanding of reaction mechanisms in photocatalysis and electrocatalysis is pivotal to facilitate these processes, and the quantitative isotope measurement provides such a toolbox. Herein, we summarize the theory of two kinds of important isotope measurements (i.e., kinetic isotope effect and isotope labeling methods) and then review their important applications in photocatalytic/electrocatalytic CO2 reduction, N2 fixation, water oxidation, oxygen reduction and organic transformations on heterogeneous catalysts. Future prospects for quantitative isotope measurements are also presented. This journal is © The Royal Society of Chemistry.
英文关键词	Carbon dioxide; Electrocatalysis; Electrolytic reduction; Molecular oxygen; Photocatalysis; Rate constants; Energy chemistry; Future prospects; Heterogeneous catalyst; Heterogeneous photocatalysis; Isotope measurements; Kinetic isotope effects; Organic transformations; Reaction mechanism; Isotopes; catalysis; catalyst; electrochemistry; heterogeneity; isotopic analysis; measurement method; photochemistry; quantitative analysis
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189563
作者单位	Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China; University of Chinese Academy of Sciences, Beijing, 100049, China
推荐引用方式 GB/T 7714	Lin Y.,Deng C.,Wu L.,et al. Quantitative isotope measurements in heterogeneous photocatalysis and electrocatalysis[J],2020,13(9).
APA	Lin Y..,Deng C..,Wu L..,Zhang Y..,Chen C..,...&Zhao J..(2020).Quantitative isotope measurements in heterogeneous photocatalysis and electrocatalysis.Energy & Environmental Science,13(9).
MLA	Lin Y.,et al."Quantitative isotope measurements in heterogeneous photocatalysis and electrocatalysis".Energy & Environmental Science 13.9(2020).