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DOI	10.1039/d0ee01100b
	Ag2Cu2O3-a catalyst template material for selective electroreduction of CO to C2+products
	Martić N.; Reller C.; Macauley C.; Löffler M.; Reichert A.M.; Reichbauer T.; Vetter K.-M.; Schmid B.; McLaughlin D.; Leidinger P.; Reinisch D.; Vogl C.; Mayrhofer K.J.J.; Katsounaros I.; Schmid G.
发表日期	2020
ISSN	17545692
起始页码	2993
结束页码	3006
卷号	13 期号:9
英文摘要	Although recent years have brought significant progress within the field of electrochemical conversion of CO2 and CO to value-added chemicals, many more challenges need to be overcome for this technology to be implemented on an industrial level. Rational design of catalyst materials that would enable selective production of desired products at industrially relevant current densities (>200 mA cm-2) is most certainly one of them. Here, we introduce Ag2Cu2O3, a mixed-metal oxide, as a starting template material for efficient electroreduction of CO to C2+ products. By combining results from electrochemical real-time mass spectrometry (EC-RTMS), XRD and XPS we confirmed the template nature of Ag2Cu2O3 and in situ formation of a fully reduced CuAg bimetallic material during the first minutes of electrolysis. Electrochemical screening of the catalyst revealed significantly varying product distributions when CO2 (CO2RR) and CO (CORR) where used as feed gases. During CORR, a faradaic efficiency close to 92% towards C2+ products at 600 mA cm-2 was achieved. On the other hand, during CO2RR, CO was found to be the main product under all tested current densities, reaching a maximum faradaic efficiency of 68%. XPS valence band spectra of the bimetallic surface originating from Ag2Cu2O3 showed that its d-band electronic structure is noticeably different compared to metallic Ag and Cu, a finding we link to the observed product distributions. Finally, additional microscopy characterization techniques were used to investigate the observed surface reconstruction of the catalyst material under reaction conditions. This journal is © The Royal Society of Chemistry.
英文关键词	Binary alloys; Carbon dioxide; Catalysts; Efficiency; Electrolytic reduction; Electronic structure; Industrial chemicals; Mass spectrometry; Metals; X ray photoelectron spectroscopy; Characterization techniques; Electrochemical conversion; Faradaic efficiencies; Product distributions; Real-time mass spectrometry; Selective production; Valence band spectra; Value-added chemicals; Product design; carbon monoxide; catalysis; catalyst; electrochemistry; reduction
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189553
作者单位	Siemens Gas and Power GmbH and Co. KG, SE NEB TP COS, Freyeslebenstr. 1, Erlangen, 91058, Germany; Department of Materials Science and Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstr. 5, Erlangen, 91058, Germany; Helmholtz Institute Erlangen-Nürnberg for Renewable Energy (IEK-11), Forschungszentrum Jülich GmbH, Egerlandstr. 3, Erlangen, 91058, Germany; Department of Chemical and Biological Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Immerwahrstr. 2a, Erlangen, 91058, Germany; Catalysis Research Center, Technical University of Munich (TUM), Ernst-Otto-Fischer-Str. 1, Garching, 85748, Germany
推荐引用方式 GB/T 7714	Martić N.,Reller C.,Macauley C.,et al. Ag2Cu2O3-a catalyst template material for selective electroreduction of CO to C2+products[J],2020,13(9).
APA	Martić N..,Reller C..,Macauley C..,Löffler M..,Reichert A.M..,...&Schmid G..(2020).Ag2Cu2O3-a catalyst template material for selective electroreduction of CO to C2+products.Energy & Environmental Science,13(9).
MLA	Martić N.,et al."Ag2Cu2O3-a catalyst template material for selective electroreduction of CO to C2+products".Energy & Environmental Science 13.9(2020).