气候变化领域集成服务门户(CCPortal): Molecular insights and concepts to engineer singlet fission energy conversion devices

CCPortal

DOI	10.1039/d0ee00495b
	Molecular insights and concepts to engineer singlet fission energy conversion devices
	Casillas R.; Papadopoulos I.; Ullrich T.; Thiel D.; Kunzmann A.; Guldi D.M.
发表日期	2020
ISSN	17545692
起始页码	2741
结束页码	2804
卷号	13 期号:9
英文摘要	In this Review, we showcase the fundamental processes of intermolecular and intramolecular singlet fission (SF). Furthermore we prioritize the information, which is relevant for the implementation of SF and SF-materials into solar energy conversion devices. We do this, firstly, by referring to the complexity of SF, and discussing key aspects of it; secondly, by mentioning the instrumental efforts, which assisted in unraveling SF in benchmark molecular building blocks such as tetracene, pentacene, and their corresponding dimers/oligomers; thirdly, by presenting a collection of SF-materials, as well as available photophysical and electrochemical data for energy conversion research. Among others, these include perylene-diimides (PDIs), diketopyrrolopyrroles (DPPs), carotenoids, conjugated polymers, and diradicaloids. This Review is rounded off by discussing pioneering contributions of SF in solar energy conversion schemes and highlighting recent developments in the field. Overall, a set of guidelines is given for new directions in SF, that is, the use of new tools to discover new SF-materials (i.e. spectroscopy, computation, machine-learning) and deposition processes (i.e. thin-films, DSSCs, OPVs) to couple SF-materials with the appropriate semiconductors. This journal is © The Royal Society of Chemistry.
英文关键词	Conjugated polymers; Data handling; Deposition; Dimers; Energy conversion; Films; Solar energy; Deposition process; Diketopyrrolopyrroles; Electrochemical data; Fission energy; Molecular building blocks; Molecular insights; Perylene diimides; Photophysical; Singlet fission; concentration (composition); equipment component; molecular analysis; performance assessment; transformation
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189546
作者单位	Department of Chemistry and Pharmacy, Center of Excellence Engineering of Advanced Materials, Friedrich-Alexander-Universität, Erlangen-Nürnberg, Germany
推荐引用方式 GB/T 7714	Casillas R.,Papadopoulos I.,Ullrich T.,et al. Molecular insights and concepts to engineer singlet fission energy conversion devices[J],2020,13(9).
APA	Casillas R.,Papadopoulos I.,Ullrich T.,Thiel D.,Kunzmann A.,&Guldi D.M..(2020).Molecular insights and concepts to engineer singlet fission energy conversion devices.Energy & Environmental Science,13(9).
MLA	Casillas R.,et al."Molecular insights and concepts to engineer singlet fission energy conversion devices".Energy & Environmental Science 13.9(2020).