气候变化领域集成服务门户(CCPortal): Two-dimensional nonlayered materials for electrocatalysis

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DOI	10.1039/d0ee01714k
	Two-dimensional nonlayered materials for electrocatalysis
	Wang Y.; Zhang Z.; Mao Y.; Wang X.
发表日期	2020
ISSN	17545692
起始页码	3993
结束页码	4016
卷号	13 期号:11
英文摘要	Creating two-dimensional (2D) geometry from nonlayered catalytic materials may significantly advance electrocatalyst design. The 2D morphology of three-dimensional lattices (2D nonlayered materials) offer large structural distortions, massive surface dangling bonds, and coordinated-unsaturated surface atoms, which can induce high surface chemical activity and promote the chemisorption of reactants and fast interfacial charge transfer, thereby enhancing the electrocatalytic performance. In this article, we review typical strategies for structural engineering and manipulation of electronic states to enable the unique electrocatalytic advantages of 2D nonlayered materials. An overview is presented on recent research advances in the development of 2D nonlayered materials for catalyzing the representative electrochemical reactions that are essential to energy and sustainability, including hydrogen evolution, oxygen evolution, oxygen reduction, and CO2 reduction. For each type of redox reactions, their unique catalytic performance and underlying mechanism are discussed. Important achievements and key challenges are also discussed. © The Royal Society of Chemistry.
英文关键词	Charge transfer; Dangling bonds; Electrocatalysis; Electrocatalysts; Electrolytic reduction; Oxygen; Redox reactions; Electrocatalytic performance; Electrochemical reactions; Interfacial charge transfer; Structural distortions; Surface chemical activity; Surface dangling bonds; Three-dimensional lattices; Two Dimensional (2 D); Morphology; carbon dioxide; catalysis; catalyst; geometry; oxygen; performance assessment; two-dimensional modeling
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189495
作者单位	Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, WI 53706, United States; Key Laboratory of Materials Physics, Ministry of Education, School of Physics and Microelectronics, Zhengzhou University, Zhengzhou, 450001, China
推荐引用方式 GB/T 7714	Wang Y.,Zhang Z.,Mao Y.,et al. Two-dimensional nonlayered materials for electrocatalysis[J],2020,13(11).
APA	Wang Y.,Zhang Z.,Mao Y.,&Wang X..(2020).Two-dimensional nonlayered materials for electrocatalysis.Energy & Environmental Science,13(11).
MLA	Wang Y.,et al."Two-dimensional nonlayered materials for electrocatalysis".Energy & Environmental Science 13.11(2020).