气候变化领域集成服务门户(CCPortal): Recent advances in developing organic electrode materials for multivalent rechargeable batteries

CCPortal

DOI	10.1039/d0ee02111c
	Recent advances in developing organic electrode materials for multivalent rechargeable batteries
	Qin K.; Huang J.; Holguin K.; Luo C.
发表日期	2020
ISSN	17545692
起始页码	3950
结束页码	3992
卷号	13 期号:11
英文摘要	Due to the low cost and abundance of multivalent metallic resources (Mg/Al/Zn/Ca), multivalent rechargeable batteries (MRBs) are promising alternatives to Li-ion and Pb-acid batteries for grid-scale stationary energy storage applications. However, the high performance of inorganic electrode materials in Li-ion batteries does not extend to MRBs, because the high charge density of multivalent cations dramatically reduces their diffusivity in the crystal lattice of inorganic materials. To achieve high-performance MRBs, organic electrode materials (OEMs) with abundant structural diversity and high structural tunability offer opportunities. This review presents an overview of the state-of-the-art OEMs in MRBs, including non-aqueous rechargeable Mg/Al/Zn and aqueous rechargeable Mg/Al/Zn/Ca batteries. The advantages, challenges, development, mechanism, structure, and performance of OEMs in MRBs are discussed in detail. To provide a comprehensive and thorough understanding of OEMs in MRBs, the correlation between molecular structure and electrochemical behavior is also summarized and discussed. This review offers insights for the rational structure design and performance optimization of advanced OEMs in MRBs. © The Royal Society of Chemistry.
英文关键词	Electrodes; Energy storage; Lead acid batteries; Electrochemical behaviors; Electrode material; Inorganic materials; Multivalent cations; Organic electrodes; Performance optimizations; Stationary energy storages; Structural diversity; Lithium-ion batteries; correlation; crystal; diffusivity; electrode; energy storage; optimization; performance assessment
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189490
作者单位	Department of Chemistry and Biochemistry, George Mason University, Fairfax, VA 22030, United States; Quantum Science and Engineering Center, George Mason University, Fairfax, VA 22030, United States
推荐引用方式 GB/T 7714	Qin K.,Huang J.,Holguin K.,et al. Recent advances in developing organic electrode materials for multivalent rechargeable batteries[J],2020,13(11).
APA	Qin K.,Huang J.,Holguin K.,&Luo C..(2020).Recent advances in developing organic electrode materials for multivalent rechargeable batteries.Energy & Environmental Science,13(11).
MLA	Qin K.,et al."Recent advances in developing organic electrode materials for multivalent rechargeable batteries".Energy & Environmental Science 13.11(2020).