气候变化领域集成服务门户(CCPortal): Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction

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DOI	10.1039/d0ee02246b
	Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction
	Andersen S.Z.; Statt M.J.; Bukas V.J.; Shapel S.G.; Pedersen J.B.; Krempl K.; Saccoccio M.; Chakraborty D.; Kibsgaard J.; Vesborg P.C.K.; Nørskov J.; Chorkendorff I.
发表日期	2020
ISSN	17545692
起始页码	4291
结束页码	4300
卷号	13 期号:11
英文摘要	Lithium-mediated nitrogen reduction is a proven method to electrochemically synthesize ammonia; yet the process has so far been unstable, and the continuous deposition of lithium limits its practical applicability. One major problem of further developing this process is that very little is understood about the mechanism. We develop a model to start understanding the kinetics and we use our understanding to develop a potential cycling procedure. We show experimentally that it improves stability of the system, and leads to a significant increase in faradaic efficiency. © The Royal Society of Chemistry.
英文关键词	Ammonia; Efficiency; Lithium; Nitrogen; System stability; Continuous deposition; Faradaic efficiencies; Nitrogen reduction; Potential cycling; Reduction; ammonia; deposition; efficiency measurement; electrochemical method; lithium; nitrogen; numerical model; reaction kinetics; reduction
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189471
作者单位	Department of Physics, Technical University of Denmark, Kongens Lyngby, Denmark; Suncat Center for Interface Science and Catalysis, Department of Chemical Engineering, Stanford University, Stanford, CA, United States
推荐引用方式 GB/T 7714	Andersen S.Z.,Statt M.J.,Bukas V.J.,et al. Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction[J],2020,13(11).
APA	Andersen S.Z..,Statt M.J..,Bukas V.J..,Shapel S.G..,Pedersen J.B..,...&Chorkendorff I..(2020).Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction.Energy & Environmental Science,13(11).
MLA	Andersen S.Z.,et al."Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction".Energy & Environmental Science 13.11(2020).