气候变化领域集成服务门户(CCPortal): Dual Carbon Isotope-Based Source Apportionment and Light Absorption Properties of Water-Soluble Organic Carbon in PM2.5 Over China

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DOI	10.1029/2020JD033920
	Dual Carbon Isotope-Based Source Apportionment and Light Absorption Properties of Water-Soluble Organic Carbon in PM2.5 Over China
	Mo Y.; Li J.; Cheng Z.; Zhong G.; Zhu S.; Tian C.; Chen Y.; Zhang G.
发表日期	2021
ISSN	2169897X
卷号	126 期号:8
英文摘要	Water-soluble organic carbon (WSOC) makes up a large fraction of organic carbon, which has attracted considerable attention due to its light absorption properties and effects on human health. However, the poorly constrained sources and light absorption properties of WSOC give rise to large uncertainties in its effects on climate and health, especially in regions with high pollutant loading. Here, we investigated the sources and light absorption properties of WSOC in 10 cities across China by dual carbon isotope analysis and UV−visible spectrophotometry, respectively. Despite a dominant contribution of nonfossil sources, the fossil source contribution to WSOC was higher in China than in other regions of the world. The average mass absorption efficiency of WSOC at 365 nm (MAE365) the fossil source contribution of WSOC were 1.13 ± 0.37 m2/gC and 39.9 ± 9.4%, respectively; both values were higher in northern than southern China. The nonfossil source contribution and δ13C of WSOC exhibited significant seasonal variations, with higher values in cold seasons, likely in association with enhanced corn residue burning. In addition, higher MAE365 in the cold seasons (fall and winter) was strongly related to enhanced biomass burning emissions. However, the fossil source contribution of WSOC showed a positive relationship with MAE365 in the cold seasons. This may be because the primary fossil WSOC emitted directly by coal combustion and the secondary fossil WSOC generated under the high NOx conditions in the cold seasons would enhance the color of the entire WSOC. To limit the impacts of WSOC on regional climate and human health, it is suggested that mitigation strategies should consider spatiotemporal variation in WSOC sources, its light absorption properties, and the various formation pathways. © 2021. American Geophysical Union. All Rights Reserved.
英文关键词	China; dual carbon isotope; light absorption properties; water soluble organic carbon
语种	英语
来源期刊	Journal of Geophysical Research: Atmospheres
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/185301
作者单位	State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China; CAS Center for Excellence in Deep Earth Science, Guangzhou, China; Key Laboratory of Coastal Zone Environmtal Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Science, Yantai, China; Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai, China
推荐引用方式 GB/T 7714	Mo Y.,Li J.,Cheng Z.,et al. Dual Carbon Isotope-Based Source Apportionment and Light Absorption Properties of Water-Soluble Organic Carbon in PM2.5 Over China[J],2021,126(8).
APA	Mo Y..,Li J..,Cheng Z..,Zhong G..,Zhu S..,...&Zhang G..(2021).Dual Carbon Isotope-Based Source Apportionment and Light Absorption Properties of Water-Soluble Organic Carbon in PM2.5 Over China.Journal of Geophysical Research: Atmospheres,126(8).
MLA	Mo Y.,et al."Dual Carbon Isotope-Based Source Apportionment and Light Absorption Properties of Water-Soluble Organic Carbon in PM2.5 Over China".Journal of Geophysical Research: Atmospheres 126.8(2021).