气候变化领域集成服务门户(CCPortal): Evolution of organic-mineral interactions and implications for organic carbon occurrence and transformation in shale

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DOI	10.1130/B35223.1
	Evolution of organic-mineral interactions and implications for organic carbon occurrence and transformation in shale
	Zhu X.; Cai J.; Wang Y.; Liu H.; Zhang S.
发表日期	2020
ISSN	167606
起始页码	784
结束页码	792
卷号	132 期号:2021-03-04
英文摘要	Organic-mineral interactions are pervasive in sedimentary environments; however, the extent of these interactions is not constant and has a significant impact on organic carbon (OC) occurrence and transformation. To understand the evolution of organic-mineral interactions and the implications for OC occurrence and transformation in fine-grained sediments, several shale samples were selected and subjected to physical and chemical sequential treatments. The samples were subjected to pyrolysis, Fourier transform infrared spectrophotometry (FTIR), and adsorption measurements to determine the organic parameters and the mineral surface area (MSA) of the shale samples. The results show that the organic fractions derived from sequential treatments have varying pyrolysis and FTIR characteristics. The correlation between the total OC content and MSA is positive, but it is split according to organic fractions with different attributes. Correlations between the different organic fractions and MSA indicate that the organic matter in shale is mainly adsorbed on mineral surfaces, while a certain portion of organic matter occurs in the pores and is adsorbed on the organic-mineral aggregates, suggesting variable interactions between the organic fractions with different attributes and minerals. From the pyrolysis and FTIR analysis, the organic fractions of different occurrence sites vary in their OC proportion, proclivity to form organic functional groups, and hydrocarbon generation potential. With increasing burial depth, the MSA and hydrogen index as well as OC loading per unit MSA are reduced, and the OC proportions of organic fractions with different attributes have regular trends. These observations indicate that the extent of organic-mineral interactions that can stabilize organic matter gradually decreases, resulting in transformation of the tightly mineral-combined OC into free OC. Our work reveals the heterogeneity in organic matter occurrence and the effect of the evolution of the organic-mineral interactions on OC occurrence and transformation, which is significant in the global carbon cycle and in petroleum systems. © 2019 Geological Society of America.
语种	英语
来源期刊	Bulletin of the Geological Society of America
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/184808
作者单位	State Key Laboratory of Marine Geology, Tongji University, Shanghai, 200092, China; Research Institute of Exploration and Development, Shengli Oilfield Company, SINOPEC, Dongying, 257015, China
推荐引用方式 GB/T 7714	Zhu X.,Cai J.,Wang Y.,et al. Evolution of organic-mineral interactions and implications for organic carbon occurrence and transformation in shale[J],2020,132(2021-03-04).
APA	Zhu X.,Cai J.,Wang Y.,Liu H.,&Zhang S..(2020).Evolution of organic-mineral interactions and implications for organic carbon occurrence and transformation in shale.Bulletin of the Geological Society of America,132(2021-03-04).
MLA	Zhu X.,et al."Evolution of organic-mineral interactions and implications for organic carbon occurrence and transformation in shale".Bulletin of the Geological Society of America 132.2021-03-04(2020).