气候变化领域集成服务门户(CCPortal): Fabrication of composite materials MIL-100(Fe)/Indonesian activated natural zeolite as enhanced CO2 capture material

CCPortal

DOI	10.1007/s11696-021-01558-2
	Fabrication of composite materials MIL-100(Fe)/Indonesian activated natural zeolite as enhanced CO2 capture material
	Lestari W.W.; Yunita L.; Saraswati T.E.; Heraldy E.; Khafidhin M.A.; Krisnandi Y.K.; Arrozi U.S.F.; Kadja G.T.M.
发表日期	2021
ISSN	3666352
英文摘要	Capturing carbon dioxide using porous materials such as zeolite and metal–organic frameworks (MOFs) could be one of the best efforts to reduce greenhouse gas emissions. This study was aimed at investigating the effect of the addition of Indonesian activated natural zeolite (ANZ) into MOF-type Materials of Institute Lavoisier (MIL-100(Fe)) on their properties and CO2 adsorption capacity. Natural zeolite was activated by acidification, which was followed by the ion exchange process. The ANZ@MIL-100(Fe) composite was synthesized by the ex situ method using sonication, with the addition of ANZ in several variations of weight for 1 h. The measurement of CO2 adsorption capacity was done by the volumetric method. The X-ray diffraction analysis showed the characteristic peaks of both ANZ and MIL-100(Fe) in the composite materials. The Fourier-transform infrared analysis exhibited absorption peaks at 1634, 1058, and 1432 cm−1 corresponding to the C=O bond from MIL-100(Fe), N–H bending, and Si–O bond of ANZ, respectively. The addition of ANZ into MIL-100(Fe) decreased the porosity, surface area, and nitrogen sorption isotherm capacity of MIL-100(Fe); however, it increased the thermal stability of MIL-100(Fe). The scanning electron microscopy–energy-dispersive X-ray analysis revealed the existence of Si and Al elements in ANZ@MIL-100(Fe). The measurement of CO2 adsorption capacity showed 300% enhancement after the addition of ANZ 20 wt% reaching up to 7.01 mmol/g. Graphic abstract: [Figure not available: see fulltext.]. © 2021, Institute of Chemistry, Slovak Academy of Sciences.
英文关键词	Activated natural zeolite; Adsorption; CO2; Composites; MIL-100(Fe)
来源期刊	Chemical Papers
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/177297
作者单位	Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir Sutami No. 36A, Kentingan-Jebres, Surakarta, Central Java 57126, Indonesia; Solid Inorganic Framework Laboratory, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok, 16424, Indonesia; Department of Chemistry, Faculty of Mathematics and Sciences, State University of Malang, Jl. Semarang 5, Malang, East Java 65145, Indonesia; Division of Inorganic and Physical Chemistry, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung, 40132, Indonesia; Center for Catalysis and Reaction Engineering, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung, 40132, Indonesia; Research Center for Nanosciences and Nanotechnology, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung, 40132, Indonesia
推荐引用方式 GB/T 7714	Lestari W.W.,Yunita L.,Saraswati T.E.,et al. Fabrication of composite materials MIL-100(Fe)/Indonesian activated natural zeolite as enhanced CO2 capture material[J],2021.
APA	Lestari W.W..,Yunita L..,Saraswati T.E..,Heraldy E..,Khafidhin M.A..,...&Kadja G.T.M..(2021).Fabrication of composite materials MIL-100(Fe)/Indonesian activated natural zeolite as enhanced CO2 capture material.Chemical Papers.
MLA	Lestari W.W.,et al."Fabrication of composite materials MIL-100(Fe)/Indonesian activated natural zeolite as enhanced CO2 capture material".Chemical Papers (2021).