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DOI10.1016/j.fuel.2020.118574
Thermochemical conversion of Polyalthia longifolia leaves at different temperatures and characterization of their products
Ahmed G.; Acharya S.; Kawale H.; Singh A.; Kishore N.; Pal S.
发表日期2020
ISSN162361
卷号280
英文摘要Lignocellulosic biomass is a renewable source of energy which can be harnessed to produce biofuels maintaining the carbon neutrality in the atmosphere. Thus, in this work, results of the pyrolysis of solid wastes of Polyalthia Longifolia (PL) leaves have been reported over a range of temperature from 450 °C to 600 °C at an interval of 50 °C. All experiments have been carried out three times in order to ensure repeatability and/or reduce measuring uncertainties; and the average values along with their standard deviation values are presented. The pyrolytic products have been thoroughly characterized by several advanced characterization techniques such as FTIR, GCMS, NMR, XRD, SEM, TGA, etc. as applicable to different products in addition to their physical and fuel properties. Further, the physical and fuel properties are reported for both individual organic and aqueous phases after separating liquid pyrolysis product; as well as based on raw liquid product obtained by pyrolysis before separating into organic and aqueous phases. The average higher heating value of organic phase bio-oil is varying in the range 21.74–24.28 MJ/kg for different pyrolysis temperatures. The moisture content of organic phase bio-oil varies between 0.36 mass % and 8.88 mass % over the temperature range of this study. The pH of organic phase bio-oil is in the range of 5.80 to 6.04 which indicate that the bio-oil is only marginally acidic; and further this range of pH is far better than their counterparts of open literature. From the GCMS analysis of bio-oil samples, it is found that phenol, 2,6-dimethoxy (syringol) is present with highest area % of 22.71 for the case of 600 °C pyrolysis temperature. Finally, the bio-oils produced from the pyrolysis of PL leaves are of good quality in terms of moderately large HHV, pH and low moisture content. © 2020 Elsevier Ltd
英文关键词Biofuels; Green chemicals; Polyalthia Longifolia; Pyrolysis; Thermochemical conversion; Waste to energy
scopus关键词Calorific value; Cellulosic ethanol; Lignocellulosic biomass; Moisture; Moisture determination; Carbon neutralities; Characterization techniques; Higher heating value; Measuring uncertainty; Pyrolysis temperature; Pyrolytic products; Standard deviation; Thermochemical Conversion; Pyrolysis
来源期刊Fuel
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/176579
作者单位Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati, Assam 781039, India; Department of Chemical Engineering, Maulana Azad National Institute of Technology Bhopal, Bhopal, Madhya Pradesh 462003, India
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Ahmed G.,Acharya S.,Kawale H.,et al. Thermochemical conversion of Polyalthia longifolia leaves at different temperatures and characterization of their products[J],2020,280.
APA Ahmed G.,Acharya S.,Kawale H.,Singh A.,Kishore N.,&Pal S..(2020).Thermochemical conversion of Polyalthia longifolia leaves at different temperatures and characterization of their products.Fuel,280.
MLA Ahmed G.,et al."Thermochemical conversion of Polyalthia longifolia leaves at different temperatures and characterization of their products".Fuel 280(2020).
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