气候变化领域集成服务门户(CCPortal): Multiresponsive UV-One-Photon Absorption; Near-Infrared-Two-Photon Absorption; and X/?-Photoelectric Absorption Luminescence in One [Cu4I4] Compound

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DOI	10.1021/acs.inorgchem.9b00876
	Multiresponsive UV-One-Photon Absorption; Near-Infrared-Two-Photon Absorption; and X/?-Photoelectric Absorption Luminescence in One [Cu4I4] Compound
	Yin S.-Y.; Wang Z.; Liu Z.-M.; Yu H.-J.; Zhang J.-H.; Wang Y.; Mao R.; Pan M.; Su C.-Y.
发表日期	2019
ISSN	201669
起始页码	10736
结束页码	10742
卷号	58 期号:16
英文摘要	A new Cu4I4-cluster-based compound is constructed to show multifaceted photoluminescent attributes: (1) ultraviolet (UV)-excited thermo-, mechano-, and rigido-chromic phosphorescence by the OPA (one-photon absorption) pathway, due to the interchanging emissions from cluster-centered (3CC) and halide-to-ligand charge-transfer (3XLCT) excited triplet states, (2) the ability to convert X/?-ray and near-infrared (NIR) radiation to visible-light emission, in which the heavy Cu4I4 cores serve as the efficient X/?-PEA (photoelectric absorption) or NIR-TPA (two-photon absorption) trapper and convertor to photons in the visible spectrum from the same emissive triplet states as those produced by UV excitation. This all-in-one compound affords a highly integrated nanolab for understanding and exploiting a wide range of photophysical phenomena simultaneously and is further fabricated into fiber-coupled long-range, in situ cryogenic thermometer and poly(methyl methacrylate) (PMMA)-embedded monolith gel, providing access to advanced applications in multifunctional optical materials and devices. American Chemical Society.
来源期刊	Inorganic Chemistry
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/176367
作者单位	MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou, Guangdong, 510275, China; School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, Shanxi, 030006, China; Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201800, China
推荐引用方式 GB/T 7714	Yin S.-Y.,Wang Z.,Liu Z.-M.,et al. Multiresponsive UV-One-Photon Absorption; Near-Infrared-Two-Photon Absorption; and X/?-Photoelectric Absorption Luminescence in One [Cu4I4] Compound[J],2019,58(16).
APA	Yin S.-Y..,Wang Z..,Liu Z.-M..,Yu H.-J..,Zhang J.-H..,...&Su C.-Y..(2019).Multiresponsive UV-One-Photon Absorption; Near-Infrared-Two-Photon Absorption; and X/?-Photoelectric Absorption Luminescence in One [Cu4I4] Compound.Inorganic Chemistry,58(16).
MLA	Yin S.-Y.,et al."Multiresponsive UV-One-Photon Absorption; Near-Infrared-Two-Photon Absorption; and X/?-Photoelectric Absorption Luminescence in One [Cu4I4] Compound".Inorganic Chemistry 58.16(2019).