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DOI10.1016/j.jclepro.2019.04.194
Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste
Lee Y.; Andrew Lin K.-Y.; Kwon E.E.; Lee J.
发表日期2019
ISSN9596526
起始页码624
结束页码633
卷号227
英文摘要Renewable chemicals, which could potentially replace crude oil-derived chemicals, have been receiving increased interest due to their environment-friendliness (i.e., carbon neutrality). Nylon 66 and nylon 6 are synthetic polymers that are widely used in daily life, synthesized by polycondensation of adipic acid and hexamethylenediamine (HMDA)and by ring-opening polymerization of ε-caprolactam, respectively. This review assesses catalytic productions of these three monomers from food waste. The food waste-based routes to the target compounds are analyzed separately and compared to conventional petroleum-based routes. Even though no commercially available methods to directly convert food waste into the target molecules exist, we have suggested emerging and promising catalytic routes via combined processes. The proposed pathways for the renewable production of adipic acid, HMDA, and ε-caprolactam are not yet fully competitive with petrochemical pathways due to higher costs and lower process efficiencies. However, considering that the renewable food waste-based routes are still being developed, their commercialization should happen soon. Elsevier Ltd
英文关键词Adipic acid; Biorefinery; Caprolactam; Catalyst; Hexamethylenediamine; Organic waste
scopus关键词Catalysts; Cyclohexane; Molecules; Nylon polymers; Oils and fats; Petrochemicals; Rayon; Adipic acids; Biorefineries; Caprolactam; Hexamethylenediamine; Organic wastes; Ring opening polymerization
来源期刊Journal of Cleaner Production
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/176188
作者单位Department of Environmental Engineering, Ajou University, Suwon, 16499, South Korea; Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture & Research Center of Sustainable Energy and Nanotechnology, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan; Department of Environment and Energy, Sejong University, Seoul, 05006, South Korea
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Lee Y.,Andrew Lin K.-Y.,Kwon E.E.,et al. Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste[J],2019,227.
APA Lee Y.,Andrew Lin K.-Y.,Kwon E.E.,&Lee J..(2019).Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste.Journal of Cleaner Production,227.
MLA Lee Y.,et al."Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste".Journal of Cleaner Production 227(2019).
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