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DOI | 10.1016/j.energy.2019.06.013 |
A study of densified biochar as carbon source in the silicon and ferrosilicon production | |
Riva L.; Surup G.R.; Buø T.V.; Nielsen H.K. | |
发表日期 | 2019 |
ISSN | 3605442 |
起始页码 | 985 |
结束页码 | 996 |
卷号 | 181 |
英文摘要 | Biochar pellets were investigated as renewable reducing agents in substitution of coal and coke in the silicon and ferrosilicon production, where a high reactivity, good mechanical properties and low feedstock costs are appreciated. The usage of pyrolysis oil as binder was investigated as way to improve the quality of the pellets. Norway spruce biochar produced at 500, 800 and 1100 °C, was pelletized blended with pyrolysis oil and lignosulphonate. A second heat treatment was carried out at the same temperatures to evaluate the interaction between biochar and pyrolysis oil and to imitate the thermal stability of the pellets when used in a furnace. Density, tensile strength and mechanical durability were analyzed before and after the second heat treatment. The CO2 reactivity was investigated under non-steady conditions. It was observed that the pellet quality is affected by the pyrolysis temperature, showing a relevant difference in properties between 500 °C and 800 °C. The combination of lignosulphonate and pyrolysis oil improved considerably the density and mechanical durability of the pellets. By the second heat treatment, the quality of the pellets was bettered significantly. Densification seems to reduce CO2 reactivity; however, pellets showed a still high reactivity. Elsevier Ltd |
英文关键词 | Biochar; Carbon neutrality; Densification; Ferrosilicon production; Pyrolysis oil; Silicon production |
scopus关键词 | Carbon; Carbon dioxide; Densification; Durability; Heat treatment; Mechanical properties; Pelletizing; Pyrolysis; Reducing agents; Silicon; Tensile strength; Thermodynamic stability; Bio chars; Carbon neutralities; Feedstock costs; High reactivity; Mechanical durability; Non-steady conditions; Pyrolysis oil; Pyrolysis temperature; Ferroalloys; biochar; carbon; industrial production; mechanical property; oil; pyrolysis; silicon; Picea abies |
来源期刊 | Energy |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/176186 |
作者单位 | Department of Engineering Sciences, University of Agder, Postboks 509, Grimstad, 4898, Norway; Elkem Technology, Fiskåveien 10, Kristiansand, 4621, Norway |
推荐引用方式 GB/T 7714 | Riva L.,Surup G.R.,Buø T.V.,et al. A study of densified biochar as carbon source in the silicon and ferrosilicon production[J],2019,181. |
APA | Riva L.,Surup G.R.,Buø T.V.,&Nielsen H.K..(2019).A study of densified biochar as carbon source in the silicon and ferrosilicon production.Energy,181. |
MLA | Riva L.,et al."A study of densified biochar as carbon source in the silicon and ferrosilicon production".Energy 181(2019). |
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