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DOI10.1029/2020GL089218
Thermodynamical Modeling of Liquid Fe-Si-Mg-O:Molten Magnesium Silicate Release From the Core
Helffrich G.; Hirose K.; Nomura R.
发表日期2020
ISSN 0094-8276
卷号47期号:21
英文摘要We developed a thermodynamic model to explore the joint solubility of Mg, Si, and O in liquid Fe on the basis of high-pressure metal-silicate partitioning data in the literature, with more Mg kept in the metal when Si and O are present. With <1.7 ± 0.5 wt% Mg, the metal in the young Earth's core retains Mg as the core evolves and crystallizes SiO2. Higher Mg concentrations require either the late addition of metal that equilibrated with silicate in a super-liquidus magma ocean or the assimilation of silicate into the core at the time of a giant impact. Above 1.7 wt% Mg, (Mg,Fe)-silicate melts also exsolve from the core and transfer core-hosted elements to the mantle. Fractional crystallization of the core-derived silicate melts in the core or at the core-mantle boundary could, additionally, yield a persistent molten silicate layer that could also contribute to ultralow velocity zone formation in the lowermost mantle. ©2020. American Geophysical Union. All Rights Reserved.
英文关键词Iron compounds; Metals; Silica; Silicates; Silicon; Structural geology; Core-mantle boundary; Fractional crystallization; Metal-silicate partitioning; Mg concentrations; Molten magnesium; Thermodynamic model; Thermodynamical model; Ultralow velocity zone; Magnesium compounds; concentration (composition); core analysis; crystallization; iron; magma; magnesium; oxygen; silicate; silicon; thermodynamics
语种英语
来源期刊Geophysical Research Letters
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/169518
作者单位Earth-Life Science Institute, Tokyo Institute of Technology, Tokyo, Japan; Department of Earth and Planetary Science, University of Tokyo, Tokyo, Japan; Now at Hakubi Center/Graduate School of Human and Environmental Studies, Kyoto University, Kyoto, Japan
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Helffrich G.,Hirose K.,Nomura R.. Thermodynamical Modeling of Liquid Fe-Si-Mg-O:Molten Magnesium Silicate Release From the Core[J],2020,47(21).
APA Helffrich G.,Hirose K.,&Nomura R..(2020).Thermodynamical Modeling of Liquid Fe-Si-Mg-O:Molten Magnesium Silicate Release From the Core.Geophysical Research Letters,47(21).
MLA Helffrich G.,et al."Thermodynamical Modeling of Liquid Fe-Si-Mg-O:Molten Magnesium Silicate Release From the Core".Geophysical Research Letters 47.21(2020).
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