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DOI10.1039/d0ee00815j
Manganese oxide-based heterogeneous electrocatalysts for water oxidation
Park S.; Lee Y.H.; Choi S.; Seo H.; Lee M.Y.; Balamurugan M.; Nam K.T.
发表日期2020
ISSN1754-5692
起始页码2310
结束页码2340
卷号13期号:8
英文摘要Water oxidation is considered an important reaction to attain sustainable energy systems. Inspired by the biological Mn4CaO5 cluster, considerable effort has been devoted to developing efficient manganese-based heterogeneous catalysts for the water oxidation reaction. This review first describes the structural characteristics of the Mn4CaO5 cluster and synthetic manganese oxides. Important features related to the electrocatalytic activity of manganese-based heterogeneous catalysts as well as recent in situ spectroscopic results for intermediate characterization are then summarized. Current understanding of the reaction mechanism at the atomic level and the rate-determining step is highlighted. Finally, future perspectives for the development of highly active and stable manganese-based water-oxidizing catalysts are proposed. © 2020 The Royal Society of Chemistry.
语种英语
scopus关键词Calcium compounds; Electrocatalysts; Manganese oxide; Oxidation; Oxides; Electrocatalytic activity; Future perspectives; Heterogeneous catalyst; Important features; Rate determining step; Reaction mechanism; Structural characteristics; Sustainable energy systems; Manganese metallography; catalysis; catalyst; detection method; electrochemical method; manganese oxide; oxidation
来源期刊Energy and Environmental Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/162713
作者单位Department of Materials Science and Engineering, Seoul National University, Seoul, 08826, South Korea; Nano Systems Institute, Seoul National University, Seoul, 08826, South Korea
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GB/T 7714
Park S.,Lee Y.H.,Choi S.,et al. Manganese oxide-based heterogeneous electrocatalysts for water oxidation[J],2020,13(8).
APA Park S..,Lee Y.H..,Choi S..,Seo H..,Lee M.Y..,...&Nam K.T..(2020).Manganese oxide-based heterogeneous electrocatalysts for water oxidation.Energy and Environmental Science,13(8).
MLA Park S.,et al."Manganese oxide-based heterogeneous electrocatalysts for water oxidation".Energy and Environmental Science 13.8(2020).
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