气候变化领域集成服务门户(CCPortal): Engineering robust metal-phenolic network membranes for uranium extraction from seawater

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DOI	10.1039/c8ee01438h
	Engineering robust metal-phenolic network membranes for uranium extraction from seawater
	Luo W.; Xiao G.; Tian F.; Richardson J.J.; Wang Y.; Zhou J.; Guo J.; Liao X.; Shi B.
发表日期	2019
ISSN	1754-5692
起始页码	607
结束页码	614
卷号	12 期号:2
英文摘要	Roughly 4 billion tons of uranium exists in the oceans, which equates to a nearly inexhaustible supply for nuclear power production. However, the extraction of uranium from seawater is highly challenging due the background high salinity and uranium's relatively low concentration (∼3 μg L -1 ). Current approaches are generally limited by either their selectivity, sustainability, or their economic competitiveness. Here we engineered a biomass-derived microporous membrane, based on the interfacial formation of robust metal-phenolic networks (MPNs), for uranium capture from seawater. These membranes displayed advantages in terms of selectivity, kinetics, capacity, and renewability in both laboratory settings and marine field-testing. The MPN-based membranes showed a greater than ninefold higher uranium extraction capacity (27.81 μg) than conventional methods during a long-term cycling extraction of 10 L of natural seawater from the East China Sea. These results, coupled with our techno-economic analysis, demonstrate that MPN-based membranes are promising economically viable and industrially scalable materials for real-world uranium extraction. © 2019 The Royal Society of Chemistry.
语种	英语
scopus关键词	Economic analysis; Membranes; Nuclear fuels; Seawater; Uranium; Uranium metallurgy; Conventional methods; Economic competitiveness; Economically viable; Low concentrations; Micro porous membranes; Nuclear power production; Techno-Economic analysis; Uranium extraction; Extraction; concentration (composition); engineering; extraction method; field method; laboratory method; membrane; metal; phenolic compound; pollutant removal; reaction kinetics; seawater; uranium; East China Sea; Pacific Ocean
来源期刊	Energy and Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/162662
作者单位	Department of Biomass and Leather Engineering, Sichuan University, Chengdu Sichuan, 610065, China; National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu Sichuan, 610065, China; Wyss Institute for Biologically Inspired Engineering, Harvard University, Boston, MA 02115, United States; College of Environment and Resources, Fuzhou University, Fuzhou Fujian, 350108, China; Department of Applied Mathematics and Statistics, Johns Hopkins University, Baltimore, MD 21287, United States; Department of Chemical Engineering, University of Melbourne, Parkville, VIC 3010, Australia
推荐引用方式 GB/T 7714	Luo W.,Xiao G.,Tian F.,et al. Engineering robust metal-phenolic network membranes for uranium extraction from seawater[J],2019,12(2).
APA	Luo W..,Xiao G..,Tian F..,Richardson J.J..,Wang Y..,...&Shi B..(2019).Engineering robust metal-phenolic network membranes for uranium extraction from seawater.Energy and Environmental Science,12(2).
MLA	Luo W.,et al."Engineering robust metal-phenolic network membranes for uranium extraction from seawater".Energy and Environmental Science 12.2(2019).