气候变化领域集成服务门户(CCPortal): Preventing phase segregation in mixed-halide perovskites: A perspective

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DOI	10.1039/d0ee00788a
	Preventing phase segregation in mixed-halide perovskites: A perspective
	Knight A.J.; Herz L.M.
发表日期	2020
ISSN	1754-5692
起始页码	2024
结束页码	2046
卷号	13 期号:7
英文摘要	Mixed-halide perovskites are ideal materials for the demanding applications of tandem solar cells and emission-tunable light-emitting diodes (LEDs) because of their high compositional flexibility and optoelectronic performance. However, one major obstacle to their use is the compositional instability some mixed-halide perovskites experience under illumination or charge-carrier injection, during which the perovskite material demixes into regions of differing halide content. Such segregation of halide ions adversely affects the electronic properties of the material and severely limits the prospects of mixed-halide perovskite technology. Accordingly, a considerable amount of research has been performed aiming to uncover the underlying mechanisms and mitigating factors of the halide segregation process. Here we present a perspective of strategies designed to reduce the effects of halide segregation in working mixed-halide perovskite devices, based on recent literature reports. We discuss a multitude of mitigating techniques, and conclude that a combination of stoichiometric engineering, crystallinity control and trap state passivation is clearly imperative for abating halide segregation. In addition, the reduction of halide vacancies and control over illumination and temperature can, to a certain extent, mitigate halide segregation. Less direct approaches, such as a change in atmospheric environment, perovskite incorporation into a nanocrystalline composition, or direct control over the crystallographic structure of the perovskite, may however prove too cumbersome to be of practical use. This perspective paves the way for the design and creation of phase-stable, mixed-halide perovskite materials for photovoltaic and LED applications. © 2020 The Royal Society of Chemistry.
语种	英语
scopus关键词	Atmospheric structure; Crystallinity; Electronic properties; Light emitting diodes; Nanocrystalline materials; Nanocrystals; Perovskite; Atmospheric environment; Charge carrier injection; Compositional instability; Crystallographic structure; Halide perovskites; Phase segregations; Segregation process; Tandem solar cells; Perovskite solar cells; concentration (composition); equipment component; fuel cell; halide; performance assessment; perovskite; phase transition
来源期刊	Energy and Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/162567
作者单位	Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, Oxford, OX13PU, United Kingdom
推荐引用方式 GB/T 7714	Knight A.J.,Herz L.M.. Preventing phase segregation in mixed-halide perovskites: A perspective[J],2020,13(7).
APA	Knight A.J.,&Herz L.M..(2020).Preventing phase segregation in mixed-halide perovskites: A perspective.Energy and Environmental Science,13(7).
MLA	Knight A.J.,et al."Preventing phase segregation in mixed-halide perovskites: A perspective".Energy and Environmental Science 13.7(2020).