气候变化领域集成服务门户(CCPortal): Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries

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DOI	10.1039/c9ee01903k
	Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries
	Huo H.; Chen Y.; Li R.; Zhao N.; Luo J.; Pereira Da Silva J.G.; Mücke R.; Kaghazchi P.; Guo X.; Sun X.
发表日期	2020
ISSN	1754-5692
起始页码	127
结束页码	134
卷号	13 期号:1
英文摘要	Solid-state batteries (SSBs) with metallic lithium (Li) anodes and nonflammable solid-state electrolytes (SSEs) are viewed as the next-generation batteries because of their potential improvement in energy density and guarantee of safety. However, even though the high-density solid garnet SSE pellets exhibit high ionic conductivity, high transference number, and large shear modulus, the unexpectedly serious occurrence of dendrite propagation remains a problem. Herein, a mixed conductive layer (MCL) consisting of electron-conductive nanoparticles embedded in an ion-conductive network is introduced at the interface between the garnet SSE and the Li anode. Such MCL not only leads to the transition from lithiophobicity to lithiophilicity, but also homogenizes the electric-field distribution inside the MCL and relieves the electronic attacks to the garnet. As a result, the Li/MCL/garnet/MCL/Li cells show a critical current density as high as 1.2 mA cm-2 and stable cycling for over 1000 h at 0.1 mA cm-2. The LiCoO2/Li cells with the MCL-protected interface show excellent cycling and rate performance at room temperature. These results demonstrate a rational design for a stable garnet/Li interface and an effective strategy to enable Li metal anodes in SSBs. © 2020 The Royal Society of Chemistry.
语种	英语
scopus关键词	Anodes; Electric fields; Garnets; Ionic conduction in solids; Lithium; Lithium batteries; Solid state devices; Solid-State Batteries; Conductive layer; Conductive nanoparticles; Conductive networks; Electric field distributions; Electronic attack; Metallic lithium; Solid-state electrolyte; Transference number; Solid electrolytes; design method; electrolyte; fuel cell; garnet; solid
来源期刊	Energy and Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/162518
作者单位	State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; University of Chinese Academy of Sciences, Beijing, 100049, China; Department of Mechanical and Materials Engineering, University of Western OntarioON N6A 5B9, Canada; College of Physics, Qingdao University, Qingdao, 266071, China; Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), Jülich, 52425, Germany
推荐引用方式 GB/T 7714	Huo H.,Chen Y.,Li R.,et al. Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries[J],2020,13(1).
APA	Huo H..,Chen Y..,Li R..,Zhao N..,Luo J..,...&Sun X..(2020).Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries.Energy and Environmental Science,13(1).
MLA	Huo H.,et al."Design of a mixed conductive garnet/Li interface for dendrite-free solid lithium metal batteries".Energy and Environmental Science 13.1(2020).