气候变化领域集成服务门户(CCPortal): Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells

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DOI	10.1039/c9ee02268f
	Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells
	Al-Ashouri A.; Magomedov A.; Roß M.; Jošt M.; Talaikis M.; Chistiakova G.; Bertram T.; Márquez J.A.; Köhnen E.; Kasparavičius E.; Levcenco S.; Gil-Escrig L.; Hages C.J.; Schlatmann R.; Rech B.; Malinauskas T.; Unold T.; Kaufmann C.A.; Korte L.; Niaura G.; Getautis V.; Albrecht S.
发表日期	2019
ISSN	1754-5692
起始页码	3356
结束页码	3369
卷号	12 期号:11
英文摘要	The rapid rise of perovskite solar cells (PSCs) is increasingly limited by the available charge-selective contacts. This work introduces two new hole-selective contacts for p-i-n PSCs that outperform all typical p-contacts in versatility, scalability and PSC power-conversion efficiency (PCE). The molecules are based on carbazole bodies with phosphonic acid anchoring groups and can form self-Assembled monolayers (SAMs) on various oxides. Besides minimal material consumption and parasitic absorption, the self-Assembly process enables conformal coverage of arbitrarily formed oxide surfaces with simple process control. The SAMs are designed to create an energetically aligned interface to the perovskite absorber without non-radiative losses. For three different perovskite compositions, one of which is prepared by co-evaporation, we show dopant-, additive-and interlayer-free PSCs with stabilized PCEs of up to 21.1%. Further, the conformal coverage allows to realize a monolithic CIGSe/perovskite tandem solar cell with as-deposited, rough CIGSe surface and certified efficiency of 23.26% on an active area of 1 cm2. The simplicity and diverse substrate compatibility of the SAMs might help to further progress perovskite photovoltaics towards a low-cost, widely adopted solar technology. This journal is © The Royal Society of Chemistry.
语种	英语
scopus关键词	Efficiency; Monolayers; Perovskite; Solar power generation; Charge selective; Conformal coverage; Material consumption; Non-radiative loss; Power conversion efficiencies; Selective contacts; Self assembly process; Tandem solar cells; Perovskite solar cells; absorbing boundary; absorption; chemical compound; detection method; efficiency measurement; energy efficiency; fuel cell; perovskite; photovoltaic system
来源期刊	Energy and Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/162356
作者单位	Young Investigator Group Perovskite Tandem Solar Cells, Helmholtz-Zentrum Berlin, Kekuléstraße 5, Berlin, 12489, Germany; Department of Organic Chemistry, Kaunas University of Technology, Radvilenu pl. 19, Kaunas, LT 50254, Lithuania; Department of Organic Chemistry, Center for Physical Sciences and Technology, Sauletekio Ave. 3, Vilnius, LT-10257, Lithuania; Institute for Silicon Photovoltaics, Helmholtz-Zentrum Berlin Kekuléstraße 5, Berlin, 12489, Germany; PVcomB, Helmholtz Zentrum Berlin Schwarzschildstr. 3, Berlin, 12489, Germany; Department of Structure and Dynamics of Energy Materials, Helmholtz-Zentrum-Berlin fur Materialien und Energie, GmbH Hahn-Meitner Platz 1, Berlin, 14109, Germany; Faculty of Electrical Engineering and Computer Science, Technical University Berlin, Marchstraße 23, Berlin, 10587, Germany
推荐引用方式 GB/T 7714	Al-Ashouri A.,Magomedov A.,Roß M.,et al. Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells[J],2019,12(11).
APA	Al-Ashouri A..,Magomedov A..,Roß M..,Jošt M..,Talaikis M..,...&Albrecht S..(2019).Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells.Energy and Environmental Science,12(11).
MLA	Al-Ashouri A.,et al."Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells".Energy and Environmental Science 12.11(2019).