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DOI | 10.1016/j.atmosres.2020.105416 |
The morphology and chemical composition of the urban PM10 near a steel plant in Apulia determined by scanning electron microscopy. Source Apportionment | |
Siciliano T.; Giua R.; Siciliano M.; Di Giulio S.; Genga A. | |
发表日期 | 2021 |
ISSN | 0169-8095 |
卷号 | 251 |
英文摘要 | PM10 samples were collected in a site of Apulia region (South-East Italy) near a steel plant when the winds were blowing from the NW and the SE to exclude and include, respectively, the contribution of the industrial source in order to study the aerosol particles in detail and attribute them to the most appropriate emission sources. Size, morphology and chemical composition of 6500 individual particles, with an equivalent spherical diameter (ESD) between 0.4 ˗ 1 μm, 1 ˗ 2.5 μm and 2.5 ˗ 10 μm, were analysed by scanning electron microscopy coupled with energy dispersive X-ray analysis (SEM - EDX). These particles were classified in the thirteen groups: aluminosilicates, silicates, iron oxides, metal oxides, iron mixtures, aluminosilicates with sulphur, calcium sulphates, silicate-sulphate mixed particles, carbonates, carbonates-silicates, soot, biological particles and carbon rich particles. Source apportionment analyses were carried out separately for the three dimensional ranges considered and for the two wind directions from North-West and South-East and nine main sources were distinguished. The soil and the soot components are higher when the wind blow from the NW than the SE, while the anthropogenic sources are evident with the wind from the SE due to the presence of iron and carbonaceous particles characterized by typical spherical shapes and chemical elements as Ca, Na and K which could to be indicative of industrial activity. The single particle analysis let better identify the emission sources that persist on the territory, attributing to them the particles characterized by peculiar morphology and chemical composition. © 2020 |
英文关键词 | Emission sources; Particulate matter; Scanning electron microscopy; Source apportionment |
语种 | 英语 |
scopus关键词 | Aluminosilicates; Carbonates; Chemical analysis; Chemical elements; Energy dispersive X ray analysis; Industrial emissions; Iron oxides; Morphology; Scanning electron microscopy; Soot; Steelmaking; Sulfur compounds; X ray diffraction analysis; Anthropogenic sources; Biological particles; Carbonaceous particles; Chemical compositions; Individual particles; Industrial activities; Single-particle analysis; Source apportionment; Particle size analysis; aerosol composition; diameter; particle size; particulate matter; power plant; scanning electron microscopy; source apportionment; Italy; Puglia |
来源期刊 | Atmospheric Research
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/162226 |
作者单位 | Department of Mathematics and Physics “Ennio De Giorgi”, University of Salento, Lecce, 73100, Italy; Regional Agency for the Environmental Prevention and Protection (ARPA Puglia), Corso Trieste 27, Bari, 70126, Italy; Department of Biological and Environmental Sciences and Technologies, University of Salento, Lecce, 73100, Italy |
推荐引用方式 GB/T 7714 | Siciliano T.,Giua R.,Siciliano M.,et al. The morphology and chemical composition of the urban PM10 near a steel plant in Apulia determined by scanning electron microscopy. Source Apportionment[J],2021,251. |
APA | Siciliano T.,Giua R.,Siciliano M.,Di Giulio S.,&Genga A..(2021).The morphology and chemical composition of the urban PM10 near a steel plant in Apulia determined by scanning electron microscopy. Source Apportionment.Atmospheric Research,251. |
MLA | Siciliano T.,et al."The morphology and chemical composition of the urban PM10 near a steel plant in Apulia determined by scanning electron microscopy. Source Apportionment".Atmospheric Research 251(2021). |
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