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DOI10.3390/nano9040626
The Effects of ZnTe:Cu Back Contact on the Performance of CdTe Nanocrystal Solar Cells with Inverted Structure
Chen, Bingchang; Liu, Junhong; Cai, Zexin; Xu, Ao; Liu, Xiaolin; Rong, Zhitao; Qin, Donghuan; Xu, Wei; Hou, Lintao; Liang, Quanbin
发表日期2019
ISSN2079-4991
卷号9期号:4
英文摘要CdTe nanocrystal (NC) solar cells have received much attention in recent years due to their low cost and environmentally friendly fabrication process. Nowadays, the back contact is still the key issue for further improving device performance. It is well known that, in the case of CdTe thin-film solar cells prepared with the close-spaced sublimation (CSS) method, Cu-doped CdTe can drastically decrease the series resistance of CdTe solar cells and result in high device performance. However, there are still few reports on solution-processed CdTe NC solar cells with Cu-doped back contact. In this work, ZnTe:Cu or Cu:Au back contact layer (buffer layer) was deposited on the CdTe NC thin film by thermal evaporation and devices with inverted structure of ITO/ZnO/CdSe/CdTe/ZnTe:Cu (or Cu)/Au were fabricated and investigated. It was found that, comparing to an Au or Cu:Au device, the incorporation of ZnTe:Cu as a back contact layer can improve the open circuit voltage (V-oc) and fill factor (FF) due to an optimized band alignment, which results in enhanced power conversion efficiency (PCE). By carefully optimizing the treatment of the ZnTe:Cu film (altering the film thickness and annealing temperature), an excellent PCE of 6.38% was obtained, which showed a 21.06% improvement compared with a device without ZnTe:Cu layer (with a device structure of ITO/ZnO/CdSe/CdTe/Au).
英文关键词nanocrystal; CdTe; Cu-doped; ZnTe; solar cells; solution processed
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
来源期刊NANOMATERIALS
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/158804
作者单位Qin, DH; Xu, W (corresponding author), South China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China.; Hou, LT (corresponding author), Jinan Univ, Guangdong Prov Key Lab Opt Fiber Sensing & Commun, Guangzhou Key Lab Vacuum Coating Technol & New En, Siyuan Lab,Dept Phys, Guangzhou 510632, Guangdong, Peoples R China.
推荐引用方式
GB/T 7714
Chen, Bingchang,Liu, Junhong,Cai, Zexin,et al. The Effects of ZnTe:Cu Back Contact on the Performance of CdTe Nanocrystal Solar Cells with Inverted Structure[J],2019,9(4).
APA Chen, Bingchang.,Liu, Junhong.,Cai, Zexin.,Xu, Ao.,Liu, Xiaolin.,...&Liang, Quanbin.(2019).The Effects of ZnTe:Cu Back Contact on the Performance of CdTe Nanocrystal Solar Cells with Inverted Structure.NANOMATERIALS,9(4).
MLA Chen, Bingchang,et al."The Effects of ZnTe:Cu Back Contact on the Performance of CdTe Nanocrystal Solar Cells with Inverted Structure".NANOMATERIALS 9.4(2019).
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