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DOI10.1039/c2jm34280d
Controlled synthesis of CdTe nanocrystals for high performanced Schottky thin film solar cells
Sun, Shi; Liu, Hongmei; Gao, Yuping; Qin, Donghuan; Chen, Junwu
发表日期2012
ISSN0959-9428
起始页码19207
结束页码19212
卷号22期号:36
英文摘要We report the synthesis of CdTe semiconductor nanocrystals (NCs) with multi-armed, rod and tetrapod shapes, developed by a facile solution process using a cadmium carboxylate as the precursor at moderate temperatures of 220-300 degrees C. It was found that the size and morphology of the CdTe NCs were related to synthesis parameters such as the reaction temperature, carboxyl chain length and carboxylic acid. Based on these CdTe NCs, photovoltaic cells (PVC) in simple Schottky diode configuration of ITO/CdTe/Al were fabricated. The performances of the CdTe NCs solar cells were found to strongly rely on the morphology and surface ligand of the CdTe NCs. The best device could show a power conversion efficiency (PCE) of 5.15% under AM 1.5G illumination at 100 mW cm(-2), which is the highest efficiency of a CdTe NC-based Schottky solar cell reported to date. Notably, in comparison to the ITO/CdTe/LiF/Al device, the device configuration of ITO/CdTe/Al showed higher efficiency and better air-stability.
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary
来源期刊JOURNAL OF MATERIALS CHEMISTRY
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/158636
作者单位Qin, DH (corresponding author), S China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China.
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GB/T 7714
Sun, Shi,Liu, Hongmei,Gao, Yuping,et al. Controlled synthesis of CdTe nanocrystals for high performanced Schottky thin film solar cells[J],2012,22(36).
APA Sun, Shi,Liu, Hongmei,Gao, Yuping,Qin, Donghuan,&Chen, Junwu.(2012).Controlled synthesis of CdTe nanocrystals for high performanced Schottky thin film solar cells.JOURNAL OF MATERIALS CHEMISTRY,22(36).
MLA Sun, Shi,et al."Controlled synthesis of CdTe nanocrystals for high performanced Schottky thin film solar cells".JOURNAL OF MATERIALS CHEMISTRY 22.36(2012).
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