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DOI10.1007/s11051-013-2053-z
Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer
Tian, Yiyao; Zhang, Yijie; Lin, Yizhao; Gao, Kuo; Zhang, Yunpeng; Liu, Kaiyi; Yang, Qianqian; Zhou, Xiao; Qin, Donghuan; Wu, Hongbin; Xia, Yuxin; Hou, Lintao; Lan, Linfeng; Chen, Junwu; Wang, Dan; Yao, Rihui
发表日期2013
ISSN1388-0764
卷号15期号:11
英文摘要CdTe nanocrystal (NC)/CdS p-n hetero-junction solar cells with an ITO/ZnO-In/CdS/CdTe/MoOx/Ag-inverted structure were prepared by using a layer-by-layer solution process. The CdS thin films were prepared by chemical bath deposition on top of ITO/ZnO-In and were found to be very compact and pin-hole free in a large area, which insured high quality CdTe NCs thin-film formation upon it. The device performance was strongly related to the CdCl2 annealing temperature and annealing time. Devices exhibited power conversion efficiency (PCE) of 3.08 % following 400 degrees C CdCl2 annealing for 5 min, which was a good efficiency for solution processed CdTe/CdS NC-inverted solar cells. By carefully designing and optimizing the CdCl2-annealing conditions (370 degrees C CdCl2 annealing for about 15 min), the PCE of such devices showed a 21 % increase, in comparison to 400 degrees C CdCl2-annealing conditions, and reached a better PCE of 3.73 % while keeping a relatively high V-OC of 0.49 V. This PCE value, to the best of our knowledge, is the highest PCE reported for solution processed CdTe-CdS NC solar cells. Moreover, the inverted solar cell device was very stable when kept under ambient conditions, less than 4 % degradation was observed in PCE after 40 days storage.
英文关键词Nanocrystals solar cells; CdTe nanocrystals; Solution processed; Inverted structure; Energy conversion
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
来源期刊JOURNAL OF NANOPARTICLE RESEARCH
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/158610
作者单位Qin, DH (corresponding author), S China Univ Technol, State Key Lab Luminescent Mat & Devices, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China.
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GB/T 7714
Tian, Yiyao,Zhang, Yijie,Lin, Yizhao,et al. Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer[J],2013,15(11).
APA Tian, Yiyao.,Zhang, Yijie.,Lin, Yizhao.,Gao, Kuo.,Zhang, Yunpeng.,...&Yao, Rihui.(2013).Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer.JOURNAL OF NANOPARTICLE RESEARCH,15(11).
MLA Tian, Yiyao,et al."Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer".JOURNAL OF NANOPARTICLE RESEARCH 15.11(2013).
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