气候变化领域集成服务门户(CCPortal): Significant influence of the intensive agricultural activities on atmospheric PM2.5 during autumn harvest seasons in a rural area of the North China Plain

CCPortal

DOI	10.1016/j.atmosenv.2020.117844
	Significant influence of the intensive agricultural activities on atmospheric PM2.5 during autumn harvest seasons in a rural area of the North China Plain
	Li X.; Zhang C.; Liu P.; Liu J.; Zhang Y.; Liu C.; Mu Y.
发表日期	2020
ISSN	13522310
卷号	241
英文摘要	The levels and composition of atmospheric PM2.5 were comprehensively investigated over an agricultural field in the North China Plain (NCP) during the autumn harvest season for the first time to reveal the influence of intensive agricultural activities on atmospheric PM2.5. In comparison with the pre-harvesting period, PM2.5 concentration increased by a factor of 1.20–1.73 during the harvesting and post-harvesting periods despite of relatively higher wind speeds. Organic carbon (OC) in PM2.5 increased most significantly, with its average concentration (and its proportion in PM2.5) increased from 9.0 μg/m3 (15.6%) during the pre-harvesting period to 18.8 μg/m3 (28.7%) during the harvesting period and to 28.8 μg/m3 (32.1%) during the post-harvesting period, implying that OC emission relating to the harvest event made conspicuous contribution to atmospheric PM2.5. The sources of OC varied significantly during the process of the harvest event, e.g., the ratio of OC to element carbon (EC) increased from 3.33 during the pre-harvesting period to 4.54 during the harvesting period and to 5.36 during the post-harvesting period. Straw crushing and agricultural machineries during the harvesting period were suspected to the major sources for the elevation of OC because of sparse fire spots around the sampling site, whereas biomass burning became the dominant contributor to atmospheric OC during the post-harvesting period. Besides OC and EC, the concentrations of Cl- and K+ were also evidently increased from the pre-harvesting period to the post-harvesting period. The remarkable elevation of both Cl- and K+ also linked with the harvest event besides biomass burning, e.g., the release from straw crushing during the harvesting period and fertilization of the compound fertilizer with NH4Cl during the post-harvesting period. The maximal concentrations of the crustal components (Na2+, Mg2+ and Ca+) appeared during the harvesting period, revealing that straw crushing for returning to the field was their important source. The atmospheric SO42− concentration exhibited a steady decreasing trend from 15.2 μg/m3 to 8.3 μg/m3, whereas NO3− concentration significantly increased from 11.2 μg/m3 during the harvesting period to 16.2 μg/m3 during the post-harvesting period. The significant increase of NO3− concentration during the post-harvesting period was mainly attributed to the fertilization event which resulted in emissions of NH3, NOx and HONO to accelerate NO3− formation. Given the considerable contribution (more than 20%) on PM2.5, the intensive agricultural activities during the harvest season in the NCP should be aroused greater attention, especially for the current disposal of crop straws and the surplus fertilization. © 2020 Elsevier Ltd
英文关键词	Carbonaceous aerosols; NCP; Source apportionment; Water-soluble ions
语种	英语
scopus关键词	Agricultural robots; Ammonia; Chlorine compounds; Crushing; Organic carbon; Plants (botany); Agricultural activities; Agricultural fields; Average concentration; Compound fertilizer; Element carbons; Harvesting periods; North China Plain; PM2.5 concentration; Harvesting; aluminum; antimony; arsenic; barium; cadmium; calcium ion; chlorine; chromium; copper; iron; lead; magnesium ion; manganese; nickel; nitrate; organic carbon; sodium ion; sulfate; titanium; vanadium; zinc; agricultural land; burning; carbon emission; concentration (composition); intensive agriculture; particulate matter; pollutant source; rural area; air pollutant; air sampling; ambient air; atmospheric dispersion; autumn; biomass production; chemical analysis; China; circadian rhythm; harvest; humidity; ion chromatography; maximum concentration; meteorology; particulate matter; priority journal; Review; rural area; sunlight; wind speed; China; North China Plain
来源期刊	Atmospheric Environment
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/144967
作者单位	Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China; Center for Excellence in Urban Atmospheric Environment, Institute of Regional Environment, Chinese Academy of Sciences, Xiamen, 361021, China; National Engineering Laboratory for VOCs Pollution Control Material & Technology, University of Chinese Academy of Sciences, Beijing, 100049, China; University of Chinese Academy of Sciences, Beijing, 100049, China
推荐引用方式 GB/T 7714	Li X.,Zhang C.,Liu P.,et al. Significant influence of the intensive agricultural activities on atmospheric PM2.5 during autumn harvest seasons in a rural area of the North China Plain[J],2020,241.
APA	Li X..,Zhang C..,Liu P..,Liu J..,Zhang Y..,...&Mu Y..(2020).Significant influence of the intensive agricultural activities on atmospheric PM2.5 during autumn harvest seasons in a rural area of the North China Plain.Atmospheric Environment,241.
MLA	Li X.,et al."Significant influence of the intensive agricultural activities on atmospheric PM2.5 during autumn harvest seasons in a rural area of the North China Plain".Atmospheric Environment 241(2020).