| DOI | 10.5194/acp-19-2209-2019
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| Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air |
| Li G.; Cheng Y.; Kuhn U.; Xu R.; Yang Y.; Meusel H.; Wang Z.; Ma N.; Wu Y.; Li M.; Williams J.; Hoffmann T.; Ammann M.; Pöschl U.; Shao M.; Su H.
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| 发表日期 | 2019
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| ISSN | 16807316
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| 起始页码 | 2209
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| 结束页码 | 2232
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| 卷号 | 19期号:4 |
| 英文摘要 | Volatile organic compounds (VOCs) play a key role in atmospheric chemistry. Emission and deposition on soil have been suggested as important sources and sinks of atmospheric trace gases. The exchange characteristics and heterogeneous chemistry of VOCs on soil, however, are not well understood. We used a newly designed differential coated-wall flow tube system to investigate the long-term variability of bidirectional air-soil exchange of 13 VOCs under ambient air conditions of an urban background site in Beijing. Sterilized soil was investigated to address physicochemical processes and heterogeneous/multiphase reactions independently from biological activity. Most VOCs revealed net deposition with average uptake coefficients (γ) in the range of 10 -7 -10 -6 (referring to the geometric soil surface area), corresponding to deposition velocities (V d ) of 0.0013-0.01cms -1 respectively. Formic acid, however, was emitted at a long-term average rate of ∼ 6 × 10 -3 nmol m -2 s -1 , suggesting that it was formed and released upon heterogeneous oxidation of other VOCs. The soilatmosphere exchange of one individual VOC species can be affected by both its surface degradation/depletion caused by surface reactions and by competitive uptake or heterogeneous formation/accommodation of other VOC species. Overall, the results show that physicochemical processing and heterogeneous oxidation on soil and soil-derived dust can act as a sink or as a source of atmospheric VOCs, depending on molecular properties and environmental conditions. © 2019 Author(s). |
| 语种 | 英语
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| scopus关键词 | air-soil interaction; ambient air; atmospheric chemistry; deposition; dust; experimental study; formic acid; oxidation; physicochemical property; soil chemistry; volatile organic compound; Beijing [China]; China |
| 来源期刊 | Atmospheric Chemistry and Physics
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| 文献类型 | 期刊论文
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| 条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/144632
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| 作者单位 | Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany; Institute for Environmental and Climate Research, Jinan University, Guangzhou, China; College of Environmental Sciences and Engineering, Peking University, Beijing, China; Research Center for Air Pollution and Health, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou, China; State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China; Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg University Mainz, Mainz, Germany; Laboratory of Environ. Chem., Paul Scherrer Institute, Villigen, 5232, Switzerland
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推荐引用方式
GB/T 7714 |
Li G.,Cheng Y.,Kuhn U.,et al. Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air[J],2019,19(4).
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| APA |
Li G..,Cheng Y..,Kuhn U..,Xu R..,Yang Y..,...&Su H..(2019).Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air.Atmospheric Chemistry and Physics,19(4).
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| MLA |
Li G.,et al."Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air".Atmospheric Chemistry and Physics 19.4(2019).
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