气候变化领域集成服务门户(CCPortal): Aromatic compounds in a semi-urban site of western India: Seasonal variability and emission ratios

CCPortal

DOI	10.1016/j.atmosres.2020.105114
	Aromatic compounds in a semi-urban site of western India: Seasonal variability and emission ratios
	Sahu L.K.; Yadav R.; Tripathi N.
发表日期	2020
ISSN	0169-8095
卷号	246
英文摘要	Ambient concentrations of benzene, toluene, and carbon-monoxide (CO) were measured at a semi-urban site in western India during the year 2015. Monthly mixing ratios of benzene, toluene, and CO were in the ranges of 0.58–1.18, 0.62–1.48, and 218–548 ppbv, respectively. In wintertime, the higher concentrations of aromatic volatile organic compounds (VOCs) and CO were due to shallower boundary layer depths and transport from polluted Indo-Gangetic Plain. The ∆toluene/∆benzene slope of 1.18 ± 0.41 ppb ppb−1 characterizes vehicle exhaust emissions. The higher values of ∆toluene/∆benzene in May coincided with the higher ambient temperatures (average ~ 35 °C) indicating emissions from evaporative sources. The emission ratios of ∆benzene/∆CO (1.82 ± 0.47 ppb ppm−1) and ∆toluene/∆CO (2.2 ± 0.72 ppb ppm−1) in the winter season are comparable to those for several urban regions of the world. The ozone formation potential and propylene-equivalent concentration of aromatics were lower than those of alkanes and alkenes measured during the same study period. Ethane (4.4 ± 3 ppbv), propane (3.4 ± 2 ppbv), and n-Butane (3.9 ± 2 ppbv), ethene (5.8 ± 3 ppbv), and propene (1.6 ± 1 ppbv) were the dominant alkane and alkene compounds measured during the study period. The composition of non-methane volatile organic compounds shows small change with the photochemical age suggesting the contributions of several other sources in addition to vehicular exhaust. The positive matrix factorization analysis suggests relatively high loadings of benzene (~30%), toluene (45%), and CO (32%), respectively from vehicle exhaust. The study highlights major contributions of vehicle exhaust, but emissions from other sources such as biomass burning, industries, evaporative loss, and biogenic are also significant. © 2020 Elsevier B.V.
英文关键词	Air Quality; Aromatic VOCs; Biomass burning; OFP; TD-GC-FID; Vehicular emission
语种	英语
scopus关键词	Aromatization; Benzene; Boundary layers; Carbon monoxide; Ethylene; Factorization; Paraffins; Particulate emissions; Propylene; Toluene; Vehicles; Volatile organic compounds; Ambient concentrations; Equivalent concentrations; Indo-Gangetic Plains; Non-methane volatile organic compounds; Ozone formation potentials; Positive Matrix Factorization; Seasonal variability; Vehicle exhaust emissions; Urban growth; air quality; aromatic hydrocarbon; atmospheric pollution; carbon monoxide; concentration (composition); ozone; seasonal variation; urban atmosphere; volatile organic compound; Gangetic Plain; India
来源期刊	Atmospheric Research
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/141796
作者单位	Physical Research Laboratory (PRL), Ahmedabad, Navrangpura 380009, India; Indian Institute of Tropical Meteorology (IITM), Pune, Pashan 411008, India; Indian Institute of Technology Gandhinagar, Gandhinagar, Palaj 382355, India
推荐引用方式 GB/T 7714	Sahu L.K.,Yadav R.,Tripathi N.. Aromatic compounds in a semi-urban site of western India: Seasonal variability and emission ratios[J],2020,246.
APA	Sahu L.K.,Yadav R.,&Tripathi N..(2020).Aromatic compounds in a semi-urban site of western India: Seasonal variability and emission ratios.Atmospheric Research,246.
MLA	Sahu L.K.,et al."Aromatic compounds in a semi-urban site of western India: Seasonal variability and emission ratios".Atmospheric Research 246(2020).