气候变化领域集成服务门户(CCPortal): Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai; China

CCPortal

DOI	10.5194/acp-20-1217-2020
	Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai; China
	Zhu J.; Wang S.; Wang H.; Jing S.; Lou S.; Saiz-Lopez A.; Zhou B.
发表日期	2020
ISSN	1680-7316
起始页码	1217
结束页码	1232
卷号	20 期号:3
英文摘要	An observation-based model coupled to the Master Chemical Mechanism (V3.3.1) and constrained by a full suite of observations was developed to study atmospheric oxidation capacity (AOC), OH reactivity, OH chain length and HOx (=OHCHO2) budget for three different ozone (O3) concentration levels in Shanghai, China. Five months of observations from 1 May to 30 September 2018 showed that the air quality level is lightly polluted or worse (Ambient Air Quality Index, AQI, of > 100) for 12 d, of which ozone is the primary pollutant for 10 d, indicating ozone pollution was the main air quality challenge in Shanghai during summer of 2018. The levels of ozone and its precursors, as well as meteorological parameters, revealed the significant differences among different ozone levels, indicating that the high level of precursors is the precondition of ozone pollution, and strong radiation is an essential driving force. By increasing the input JNO2 value by 40 %, the simulated O3 level increased by 30 %-40 % correspondingly under the same level of precursors. The simulation results show that AOC, dominated by reactions involving OH radicals during the daytime, has a positive correlation with ozone levels. The reactions with non-methane volatile organic compounds (NMVOCs; 30 %-36 %), carbon monoxide (CO; 26 %-31 %) and nitrogen dioxide (NO2; 21 %-29 %) dominated the OH reactivity under different ozone levels in Shanghai. Among the NMVOCs, alkenes and oxygenated VOCs (OVOCs) played a key role in OH reactivity, defined as the inverse of the OH lifetime. A longer OH chain length was found in clean conditions primarily due to low NO2 in the atmosphere. The high level of radical precursors (e.g., O3, HONO and OVOCs) promotes the production and cycling of HOx, and the daytime HOx primary source shifted from HONO photolysis in the morning to O3 photolysis in the afternoon. For the sinks of radicals, the reaction with NO2 dominated radical termination during the morning rush hour, while the reactions of radical-radical also contributed to the sinks of HOx in the afternoon. Furthermore, the top four species contributing to ozone formation potential (OFP) were HCHO, toluene, ethylene and m/p-xylene. The concentration ratio (∼ 23 %) of these four species to total NMVOCs is not proportional to their contribution (∼ 55 %) to OFP, implying that controlling key VOC species emission is more effective than limiting the total concentration of VOC in preventing and controlling ozone pollution. © 2020 Author(s).
语种	英语
scopus关键词	air quality; atmospheric pollution; concentration (composition); hydroxyl radical; modeling; oxidation; ozone; photochemistry; reaction kinetics; China; Shanghai
来源期刊	Atmospheric Chemistry and Physics
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/141574
作者单位	Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP), Department of Environmental Science and Engineering, Fudan University, Shanghai, China; Institute of Eco-Chongming (IEC), No. 20 Cuiniao Road, Shanghai, 202162, China; State Environ. Protect. Key Lab. of the Formation and Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental Sciences, Shanghai, 200233, China; Institute of Atmospheric Sciences, Fudan University, Shanghai, 200433, China; Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano (CSIC), Madrid, 28006, Spain
推荐引用方式 GB/T 7714	Zhu J.,Wang S.,Wang H.,et al. Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai; China[J],2020,20(3).
APA	Zhu J..,Wang S..,Wang H..,Jing S..,Lou S..,...&Zhou B..(2020).Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai; China.Atmospheric Chemistry and Physics,20(3).
MLA	Zhu J.,et al."Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai; China".Atmospheric Chemistry and Physics 20.3(2020).