气候变化领域集成服务门户(CCPortal): Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O3 in the Arctic

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DOI	10.5194/acp-20-7335-2020
	Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O3 in the Arctic
	Huang J.; Jaeglé L.; Chen Q.; Alexander B.; Sherwen T.; Evans M.J.; Theys N.; Choi S.
发表日期	2020
ISSN	1680-7316
起始页码	7335
结束页码	7358
卷号	20 期号:12
英文摘要	We use the GEOS-Chem chemical transport model to examine the influence of bromine release from blowingsnow sea salt aerosol (SSA) on springtime bromine activation and O3 depletion events (ODEs) in the Arctic lower troposphere. We evaluate our simulation against observations of tropospheric BrO vertical column densities (VCDtropo) from the GOME-2 (second Global Ozone Monitoring Experiment) and Ozone Monitoring Instrument (OMI) spaceborne instruments for 3 years (2007-2009), as well as against surface observations of O3. We conduct a simulation with blowingsnow SSA emissions from first-year sea ice (FYI; with a surface snow salinity of 0.1 psu) and multi-year sea ice (MYI; with a surface snow salinity of 0.05 psu), assuming a factor of 5 bromide enrichment of surface snow relative to seawater. This simulation captures the magnitude of observed March-April GOME-2 and OMI VCDtropo to within 17 %, as well as their spatiotemporal variability (r D 0:76-0.85). Many of the large-scale bromine explosions are successfully reproduced, with the exception of events in May, which are absent or systematically underpredicted in the model. If we assume a lower salinity on MYI (0.01 psu), some of the bromine explosions events observed over MYI are not captured, suggesting that blowing snow over MYI is an important source of bromine activation. We find that the modeled atmospheric deposition onto snow-covered sea ice becomes highly enriched in bromide, increasing from enrichment factors of ~ 5 in September-February to 10-60 in May, consistent with composition observations of freshly fallen snow. We propose that this progressive enrichment in deposition could enable blowing-snow-induced halogen activation to propagate into May and might explain our late-spring underestimate in VCDtropo. We estimate that the atmospheric deposition of SSA could increase snow salinity by up to 0.04 psu between February and April, which could be an important source of salinity for surface snow on MYI as well as FYI covered by deep snowpack. Inclusion of halogen release from blowing-snow SSA in our simulations decreases monthly mean Arctic surface O3 by 4-8 ppbv (15 %-30 %) in March and 8-14 ppbv (30 %-40 %) in April. We reproduce a transport event of depleted O3 Arctic air down to 40 N observed at many sub-Arctic surface sites in early April 2007. While our simulation captures 25 %-40 % of the ODEs observed at coastal Arctic surface sites, it underestimates the magnitude of many of these events and entirely misses 60 %-75 % of ODEs. This difficulty in reproducing observed surface ODEs could be related to the coarse horizontal resolution of the model, the known biases in simulating Arctic boundary layer exchange processes, the lack of detailed chlorine chemistry, and/or the fact that we did not include direct halogen activation by snowpack chemistry. © 2020 Author(s).
语种	英语
scopus关键词	aerosol; bromide; computer simulation; concentration (composition); numerical model; oxygen; seasonal variation; source apportionment; spatiotemporal analysis; Arctic
来源期刊	Atmospheric Chemistry and Physics
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/141256
作者单位	Department of Atmospheric Sciences, University of Washington, Seattle, WA 98115, United States; Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, United Kingdom; National Centre for Atmospheric Science, University of York, York, YO10 5DD, United Kingdom; Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium; Science Systems and Applications Inc., Lanham, MD 20706, United States; NASA Goddard Space Flight Center, Greenbelt, MD 20771, United States; Department of Chemistry, University of Michigan, Ann Arbor, MI 48109, United States
推荐引用方式 GB/T 7714	Huang J.,Jaeglé L.,Chen Q.,et al. Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O3 in the Arctic[J],2020,20(12).
APA	Huang J..,Jaeglé L..,Chen Q..,Alexander B..,Sherwen T..,...&Choi S..(2020).Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O3 in the Arctic.Atmospheric Chemistry and Physics,20(12).
MLA	Huang J.,et al."Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O3 in the Arctic".Atmospheric Chemistry and Physics 20.12(2020).