气候变化领域集成服务门户(CCPortal): Effects of SO2 on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions

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DOI	10.5194/acp-20-4477-2020
	Effects of SO2 on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions
	Zhang W.; Wang W.; Li J.; Peng C.; Li K.; Zhou L.; Shi B.; Chen Y.; Liu M.; Ge M.
发表日期	2020
ISSN	16807316
起始页码	4477
结束页码	4492
卷号	20 期号:7
英文摘要	Secondary organic aerosol (SOA) has great impacts on air quality, climate change and human health. The composition and physicochemical properties of SOA differ greatly because they form under different atmospheric conditions and from various precursors as well as differing oxidation. In this work, photooxidation experiments of toluene were performed under four conditions (dry, dry with SO2, wet and wet with SO2) to investigate the effect of SO2 under different relative humidities on the composition and optical properties of SOA at wavelengths of 375 and 532 nm. According to our results, the increase in humidity enhances not only light absorption but also the scattering property of the SOA. Oligomers formed through multiphase reactions might be the reason for this phenomenon. Adding SO2 slightly lowers the real part of the complex refractive index, RI(n), of toluene-derived SOA (RI(n)dry; SO2< RI.n/dry, RI(n)wet; SO2< RI.n/wet), which might be a result of the partitioning of low-oxidation-state products. The imaginary part of the complex refractive index, RI(k), is enhanced under dry conditions with SO2 compared to that of only dry conditions, which might be due to acid-catalyzed aldol condensation reactions. Wet conditions with SO2shows the combined effect of SO2 and humidity. The extinction properties of toluene-derived SOA under wet conditions with SO2 increased by approximately 30% compared to that of toluene-derived SOA formed under dry conditions. Our results suggest that various atmospheric conditions will affect the composition and optical proprieties of SOA, which has significant implications for evaluating the impacts of SOA on the rapid formation of regional haze, global radiative balance and climate change. © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License.
关键词	aerosol aerosol composition air quality climate change formation mechanism haze optical property photooxidation physicochemical property radiation balance relative humidity sulfur dioxide toluene
语种	英语
来源机构	Atmospheric Chemistry and Physics
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/132096
推荐引用方式 GB/T 7714	Zhang W.,Wang W.,Li J.,et al. Effects of SO2 on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions[J]. Atmospheric Chemistry and Physics,2020,20(7).
APA	Zhang W..,Wang W..,Li J..,Peng C..,Li K..,...&Ge M..(2020).Effects of SO2 on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions.,20(7).
MLA	Zhang W.,et al."Effects of SO2 on optical properties of secondary organic aerosol generated from photooxidation of toluene under different relative humidity conditions".20.7(2020).