气候变化领域集成服务门户(CCPortal): Halogenated flame retardants in atmospheric particles from a North African coastal city (Bizerte, Tunisia): Pollution characteristics and human exposure

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DOI	10.1016/j.apr.2020.01.011
	Halogenated flame retardants in atmospheric particles from a North African coastal city (Bizerte, Tunisia): Pollution characteristics and human exposure
	Barhoumi B.; Tedetti M.; Peris A.; Guigue C.; Aznar-Alemany Ò.; Touil S.; Driss M.R.; Eljarrat E.
发表日期	2020
ISSN	13091042
英文摘要	In the present study, atmospheric particle samples were collected between September 2015 and February 2016 from Bizerte city (Tunisia) to investigate the occurrence, potential sources and impacts of a range of flame retardants (FRs), including hexabromocyclododecane diastereoisomers (HBCDDs), new halogenated flame retardants (NHFRs), as well as methoxylated polybrominated diphenyl ethers (MeO-BDEs). Among 19 examined compounds, 9 congeners (α-HBCDD, β-HBCDD, γ-HBCDD, HBB, DBDPE, syn-DP, anti-DP, 2′-MeO-BDE-68 and 6-MeO-BDE-47) were detected in atmospheric particles at different levels and frequencies. Overall, the average concentration of NHFRs (1.53 pg m−3) was 1.5 and 51 folds higher than that of HBCDDs (1.04 pg m−3) and MeO-BDEs (0.03 pg m−3), respectively. By comparison with other areas of the world, NHFRs and HBCDDs in Bizerte were at medium pollution level, while MeO-BDEs were at lower levels. No significant correlations were found between NHFR, HBCDD and MeO-BDE concentrations, suggesting different sources related on one hand to the biogenic origin of MeO-BDE, and on the other hand to various types and utilisations of imported NHFR- and HBCDD-containing products, as Tunisia does not manufacture FRs. DP and HBCDD diastereoisomer profiles appeared to be divergent from their commercial products, pointing out that a complex degradation or stereoselective transformation processes occurring in ambient air around Bizerte city. The estimated daily human exposure dose (DED) to particle-bound HBCDDs, NHFRs and MeO-BDEs via outdoor air inhalation was generally at low levels. Hence, this study reports for the first time the occurrence and potential impact of HBCDDs, NHFRs and MeO-BDEs in atmospheric particles from North Africa. © 2020 Turkish National Committee for Air Pollution Research and Control
英文关键词	Atmospheric particles; Dry deposition; Halogenated flame retardants; Human exposure; Methoxylated bromodiphenyl ethers; North Africa
语种	英语
来源期刊	Atmospheric Pollution Research
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/120642
作者单位	Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), Department of Chemistry, Faculty of Sciences of Bizerte, University of Carthage, Zarzouna, 7021, Tunisia; Water, Environmental and Food Chemistry, Department of Environmental Chemistry, IDAEA-CSIC, Jordi Girona 18-26, Barcelona, 08034, Spain; Aix Marseille Univ., Université de Toulon, CNRS, IRD, MIO UM 110, Marseille, 13288, France
推荐引用方式 GB/T 7714	Barhoumi B.,Tedetti M.,Peris A.,et al. Halogenated flame retardants in atmospheric particles from a North African coastal city (Bizerte, Tunisia): Pollution characteristics and human exposure[J],2020.
APA	Barhoumi B..,Tedetti M..,Peris A..,Guigue C..,Aznar-Alemany Ò..,...&Eljarrat E..(2020).Halogenated flame retardants in atmospheric particles from a North African coastal city (Bizerte, Tunisia): Pollution characteristics and human exposure.Atmospheric Pollution Research.
MLA	Barhoumi B.,et al."Halogenated flame retardants in atmospheric particles from a North African coastal city (Bizerte, Tunisia): Pollution characteristics and human exposure".Atmospheric Pollution Research (2020).