CCPortal
DOI10.1021/acssuschemeng.9b01603
To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol
Jens, Christian M.1; Mueller, Leonard1; Leonhard, Kaei1; Bardow, Andre1,2
发表日期2019
ISSN2168-0485
卷号7期号:14页码:12270-12280
英文摘要

Utilizing CO2 to produce value-added chemicals can save environmental and economic impacts. However, these savings are reduced by the cost of CO2 supply when CO2 has to be captured from dilute sources. To reduce the cost of CO2 supply, the combination of CO2 capture and utilization has been suggested in a single integrated CO2 capture and utilization (ICCU) process. Although integration is intuitively appealing, a rigorous assessment of the savings by integration is missing. In this work, we evaluate if integration indeed increases savings, by comparing a utilization process without integration to a novel ICCU process. In the novel ICCU process, methanol absorbs CO2 from raw natural gas, before the mixture of CO2 and methanol is hydrogenated to methyl formate. We show that the novel ICCU process saves up to 46% of the electricity demand, which results in savings of up to 8 and 7% in the cost and the greenhouse gas emissions of the utilities, respectively. However, these savings are only enabled when raw natural gas with 30 mol % CO2 is employed; with lower CO2 concentrations, integration can even increase the cost and emissions of CCU. From the obtained results, we derive an indicator to assess the savings potential of ICCU processes. Finally, life cycle assessment reveals that CO2-based methyl formate has the potential to reduce both the global warming impact and the depletion of fossil resources compared to methyl formate produced from fossil sources.


WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
来源期刊ACS SUSTAINABLE CHEMISTRY & ENGINEERING
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/100488
作者单位1.Rhein Westfal TH Aachen, Lehrstuhl Tech Thermodynam, Schinkelstr 8, D-52062 Aachen, Germany;
2.Forschungszentrum Julich, Inst Energy & Climate Res Energy Syst Engn IEK 10, Julich, Germany
推荐引用方式
GB/T 7714
Jens, Christian M.,Mueller, Leonard,Leonhard, Kaei,et al. To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol[J],2019,7(14):12270-12280.
APA Jens, Christian M.,Mueller, Leonard,Leonhard, Kaei,&Bardow, Andre.(2019).To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(14),12270-12280.
MLA Jens, Christian M.,et al."To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.14(2019):12270-12280.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Jens, Christian M.]的文章
[Mueller, Leonard]的文章
[Leonhard, Kaei]的文章
百度学术
百度学术中相似的文章
[Jens, Christian M.]的文章
[Mueller, Leonard]的文章
[Leonhard, Kaei]的文章
必应学术
必应学术中相似的文章
[Jens, Christian M.]的文章
[Mueller, Leonard]的文章
[Leonhard, Kaei]的文章
相关权益政策
暂无数据
收藏/分享

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。